NEW MOLECULAR REARRANGEMENT OF TRICYCLIC SPIROFURANOID INTO THE ALPHA,ALPHA-DISUBSTITUTED P-SEMIQUINOID SYSTEM

Authors
SERGEEV SV NIKANOROV VA KHARITONOV VG YANOVSKY AI STRUCHKOV YT ROZENBERG VI REUTOV OA
Citation
Sv. Sergeev et al., NEW MOLECULAR REARRANGEMENT OF TRICYCLIC SPIROFURANOID INTO THE ALPHA,ALPHA-DISUBSTITUTED P-SEMIQUINOID SYSTEM, Russian chemical bulletin, 45(6), 1996, pp. 1499-1501
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
6
Year of publication
1996
Pages
1499 - 1501
Database
ISI
SICI code
1066-5285(1996)45:6<1499:NMROTS>2.0.ZU;2-K
Abstract
A new acid-catalyzed molecular rearrangement of Z-2,3,4,5,6,7-hexahydr o-3-methoxy-carbonyl-4 hylspiro[benzofuran-2,1'-[2,5]cyclohexadien]-4- one into nyl)(methoxycarbonyl)methylene]-2,5-cyclohexadiene was found. The structure of the latter compound was confirmed analytically, by s pectral data, and by X-ray diffraction study.