MAGNETIC-PROPERTIES OF 4-METHYLPYRIMIDINE-BRIDGED AND 5-METHYLPYRIMIDINE-BRIDGED COPPER(II) COMPLEXES

Authors
NAKAGAWA M ISHIKAWA Y KOGANE T ISHIDA T YASUI M IWASAKI F NOGAMI T
Citation
M. Nakagawa et al., MAGNETIC-PROPERTIES OF 4-METHYLPYRIMIDINE-BRIDGED AND 5-METHYLPYRIMIDINE-BRIDGED COPPER(II) COMPLEXES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 285, 1996, pp. 351-356
Citations number
22
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
285
Year of publication
1996
Pages
351 - 356
Database
ISI
SICI code
1058-725X(1996)285:<351:MO4A5>2.0.ZU;2-X
Abstract
The magnetic measurements of [L . Cu(hfac)(2)](n) (L = 4- and 5-MPM, M PM = methylpyrimidine) revealed the presence of ferromagnetic interact ions among Cu(II) spins. However, Cu spins in di- and trinuclear compl exes were proved to be paramagnetic. The crystal structures of [4-MPM . Cu(hfac)(2)](n) and (4-MPM) (2) .[Cu(hfac)(2)](3) were determined.