SYNTHESES AND MAGNETIC-PROPERTIES OF DYE INCLUDED ORGANOMETALLIC MAGNETS - DAMS[MCR(OX)(3)]

Authors
GU ZZ SATO O IYODA T HASHIMOTO K FUJISHIMA A
Citation
Zz. Gu et al., SYNTHESES AND MAGNETIC-PROPERTIES OF DYE INCLUDED ORGANOMETALLIC MAGNETS - DAMS[MCR(OX)(3)], Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 285, 1996, pp. 469-474
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
285
Year of publication
1996
Pages
469 - 474
Database
ISI
SICI code
1058-725X(1996)285:<469:SAMODI>2.0.ZU;2-Z
Abstract
A series of dye-included metal complex-based magnets, DAMS[MCr (ox)(3) ] (DAMS(+) = (4-dimethylaminophenyl)ethenyl]-1-methylpyridinium cation ; M(2+)=Mn2+, Fe2+, Ni2+; ox(2)-=Oxalate Ion), were synthesized. In th ese compounds different kinds of metal cations are bridged to each oth er by ox(2-) ions. The compounds have a layered-structure and molecule s of DAMS(+) are enclathrated between the layers. Field-cooled magneti zation (FCM) measurement showed that these compounds exhibit magnetic phase transition at 10K, 14K, and 18K respectively.