T. Kawasaki et al., LUMINESCENCE OF SCHIFF-BASES IN SOLID-STATE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 285, 1996, pp. 579-584
We prepared a series of schiff base compounds and investigated lumines
cence spectra of these compounds in the solid state. The schiff base c
ompounds composed of phenyl rings with a hydroxyl group at an ortho po
sition, imino groups and a butane or octane bridge show very strong lu
minescence in the solid state. For example, Msalbn (19) obtained from
2-hydroxy-acetophenone and 1,4-diaminobutane (excitation wavelength =
396 nm, emission wavelength = 496 nm, relative intensity = 38.02) and
p-Me-anil (21) obtained from salicylaldehyde and p-toluidine (excitati
on wavelength = 396 nm, emission wavelength = 545.5 nm, relative inten
sity = 33.79) showed the strongest intensities in the luminescence. It
was expected that luminescence properties of the compounds in the sol
id state were affected by molecular structure, intermolecular interact
ion and a type of the aggregation of molecules.