We have investigated for the first time the complete temperature depen
dence of the upper critical field H-c2 in 2D layered superconductors t
aking both the orbital and Pauli limits into account. It is demonstrat
ed that in 2D superconductors the formation of the non-uniform Fulde-F
errell-Larkin-Ovchinnikov (FFLO) phase gives rise to an unusual temper
ature dependence of H-c2: for fields exactly parallel to the layers, H
-c2 has a linear temperature dependence as T --> 0; for any other fiel
d orientation, provided that the initial slope of the critical field a
t T = T-c is large, we predict at low temperature the appearance of a
multiquanta vortex state, revealed by the oscillatory temperature depe
ndence of H-c2. Such a new effect could be observed in low-T-c quasi-2
D layered superconductors.