W. Ensinger, ION-BEAM SPUTTER COATING OF TANTALUM TUBE INNER WALLS FOR PROTECTION AGAINST HYDROGEN EMBRITTLEMENT, Surface & coatings technology, 84(1-3), 1996, pp. 434-438
Tantalum, which is used in the chemical industry as a construction mat
erial, suffers from hydrogen embrittlement when it is corroded in cont
act with acids. In order to prevent tantalum tubes from embrittlement,
their inner walls were sputter coated with platinum films by ion bomb
ardment of a conical sputter target inside the tube. Electrochemical a
nd immersion corrosion tests show that the deposited platinum films re
duce the uptake of hydrogen and the embrittlement of the tantalum tube
s by a factor of five.