THERMODYNAMIC RELATIONSHIPS ON COMPLEX-FORMATION .3. DELTA-H-DELTA-S INTERPLAY IN THE EQUILIBRIA FOR THE FORMATION OF AMINE COMPLEXES IN AQUEOUS-SOLUTION

Authors
DEMARCO D GIANNETTO A LINERT W
Citation
D. Demarco et al., THERMODYNAMIC RELATIONSHIPS ON COMPLEX-FORMATION .3. DELTA-H-DELTA-S INTERPLAY IN THE EQUILIBRIA FOR THE FORMATION OF AMINE COMPLEXES IN AQUEOUS-SOLUTION, Thermochimica acta, 286(2), 1996, pp. 387-397
Citations number
24
Categorie Soggetti
Chemistry Analytical
Journal title
Thermochimica acta → ACNP
ISSN journal
00406031
Volume
286
Issue
2
Year of publication
1996
Pages
387 - 397
Database
ISI
SICI code
0040-6031(1996)286:2<387:TROC.D>2.0.ZU;2-I
Abstract
Delta H-Delta S values for the protonation and complexing reaction ser ies of amines in aqueous solution have been inspected for the occurren ce of functional relationships or regular patterns. Both non-linear an d anti-compensative relationships have been evidenced.