CHLOROSULPHONYL GROUP AS A NEW FUNCTIONALITY ON FULLERENES - [2-CYCLOADDITION OF CHLOROSULPHONYLISOCYANATE TO C-60(2])

Authors
MUTHU S MARUTHAMUTHU P
Citation
S. Muthu et P. Maruthamuthu, CHLOROSULPHONYL GROUP AS A NEW FUNCTIONALITY ON FULLERENES - [2-CYCLOADDITION OF CHLOROSULPHONYLISOCYANATE TO C-60(2]), Fullerene science and technology, 4(5), 1996, pp. 1061-1066
Citations number
13
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
4
Issue
5
Year of publication
1996
Pages
1061 - 1066
Database
ISI
SICI code
1064-122X(1996)4:5<1061:CGAANF>2.0.ZU;2-M
Abstract
The chlorosulphonylisocyanate reacts smoothly with C-60 in xylene unde r thermal conditions in a [2+2]-cycloaddition fashion to yield the bis adduct as one of the products in the inseparable reaction mixture. The reaction product is analysed by FAB-MS, C-13 NMR, FT-IR and HPLC tech niques. Results show the formation of imino-lactone as one of the favo urable products.