P. Facci et al., ROOM-TEMPERATURE SINGLE-ELECTRON JUNCTION, Proceedings of the National Academy of Sciences of the United Statesof America, 93(20), 1996, pp. 10556-10559
The design, realization, and test performances of an electronic juncti
on based on single-electron phenomena that works in the air at room te
mperature are hereby reported, The element consists of an electrochemi
cally etched sharp tungsten stylus over whose tip a nanometer-size cry
stal was synthesized, Langmuir-Blodgett films of cadmium arachidate we
re transferred onto the stylus and exposed to a H2S atmosphere to yiel
d CdS nanocrystals (30-50 Angstrom in diameter) imbedded into an organ
ic matrix. The stylus, biased with respect to a flat electrode, was br
ought to the tunnel distance from the film and a constant gap value wa
s maintained by a piezo-electric actuator driven by a feedback circuit
fed by the tunneling current. With this set-up, it is possible to mea
sure the behavior of the current flowing through the quantum dot when
a bias voltage is applied. Voltage-current characteristics measured in
the system displayed single-electron trends such as a Coulomb blockad
e and Coulomb staircase and revealed capacitance values as small as 10
(-19) F.