PHASE-DIAGRAMS OF PERHYDROTRIPHENYLENE AND AROMATIC-COMPOUNDS .1. TRANS STYLBENE AND 4H-CYCLOPENTA[2,1-B 3,4-B'] DITHIOPHENE/

Citation
G. Disilvestro et al., PHASE-DIAGRAMS OF PERHYDROTRIPHENYLENE AND AROMATIC-COMPOUNDS .1. TRANS STYLBENE AND 4H-CYCLOPENTA[2,1-B 3,4-B'] DITHIOPHENE/, Journal of thermal analysis, 47(1), 1996, pp. 273-280
Citations number
30
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
03684466
Volume
47
Issue
1
Year of publication
1996
Pages
273 - 280
Database
ISI
SICI code
0368-4466(1996)47:1<273:POPAA.>2.0.ZU;2-M
Abstract
Perhydrotriphenylene (PHTP) forms channel-like adducts with molecules of different size and molecular weight. In the crystal structure of th e adduct the included long sequences of molecules are separated from e ach other by the channel walls. The optical properties of the included molecules differ from those of the bulk molecules. The phase diagram of mixtures of PHTP and trans stylbene and 4H-cyclopenta [2,1-b:3,4-b' ] dithiophene (CPDT) were determined by DSC experiments. Ideality in t he liquid phase was observed only in the PHTP/CPDT system.