Yj. Park et al., COMPENSATION CENTER OF CR3+ IN GAAS CODOPED WITH CR AND IN FOR OBTAINING A SEMIINSULATING PROPERTY, Solid state communications, 101(4), 1997, pp. 219-223
The dependences of Cr2+ and Cr3+ electron paramagnetic resonance (EPR)
signals as a function of Cr concentration have been investigated in c
onjunction with clarifying the atomic configuration for obtaining semi
-insulating properties in a vertical gradient freeze (VGF)-GaAs single
crystal codoped with Cr and In (VGF-GaAs:Cr,In). Cr2+ EPR signals are
observed in both samples of semi-insulating and semiconducting GaAs:
Cr,In single crystals, whereas Cr3+ EPR signals can be observed only i
n semi-insulating samples. The semi-insulating properties become obvio
us when increasing the intensity of Cr3+ and Cr2+ EPR signals in VGF-G
aAs:Cr,In crystals. Isolated Cr-Ga(3+) ions play an important role in
GaAs as a charge compensation center for obtaining semi-insulating pro
perty. Copyright (C) 1996 Elsevier Science Ltd