RESIDUAL FILM DYNAMICS IN GLASS-CAPILLARIES

Citation
M. Cachile et al., RESIDUAL FILM DYNAMICS IN GLASS-CAPILLARIES, Journal of colloid and interface science, 182(2), 1996, pp. 483-491
Citations number
18
Categorie Soggetti
Chemistry Physical
ISSN journal
00219797
Volume
182
Issue
2
Year of publication
1996
Pages
483 - 491
Database
ISI
SICI code
0021-9797(1996)182:2<483:RFDIG>2.0.ZU;2-B
Abstract
We report measurements of the residual film thickness profiles resulti ng from the displacement of a fluid by an immiscible fluid in a 50-cm- long and 1.1-mm i.d. capillary tube. A radioactive tracer technique is used to measure the variations of the local thickness along the tube, Spatial variations of the film thickness are observed experimentally increasing with the viscosity ratio M=mu(2)/mu(1) between the displaci ng and displaced fluids (10(-3)<M<30), with the capillary number Ca (5 x10(-6)<Ca<3) and with the distance from the meniscus tip (up to 70 cm ). The thickness along the tube is constant only for low M values and/ or low Ca values. The film thickness averaged over the tube length inc reases with the capillary number as Ca-0.6: this variation is independ ent of the relative viscosity of the fluids and very similar to the ob servations of other authors using different sets of fluids. Differenti al equations verified by the film thickness variations with time and d istance far from the meniscus tip are established and their relations with the observed results are discussed. (C) 1996 Academic Press, Inc.