SYNTHESIS AND STRUCTURE OF THE BIS(AMIDO)SODATE SALT NA[NA(N(SIME(3))(2)ALME(3))(2)] - AN NA-DOT-CENTER-DOT-CENTER-DOT-H3C- INTERACTIONS( ION COMPLEXED SOLELY BY NA+CENTER)

Authors
NIEMEYER M POWER PP
Citation
M. Niemeyer et Pp. Power, SYNTHESIS AND STRUCTURE OF THE BIS(AMIDO)SODATE SALT NA[NA(N(SIME(3))(2)ALME(3))(2)] - AN NA-DOT-CENTER-DOT-CENTER-DOT-H3C- INTERACTIONS( ION COMPLEXED SOLELY BY NA+CENTER), Organometallics, 15(20), 1996, pp. 4107-4109
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
20
Year of publication
1996
Pages
4107 - 4109
Database
ISI
SICI code
0276-7333(1996)15:20<4107:SASOTB>2.0.ZU;2-O
Abstract
The synthesis and structural characterization of the sodium amide salt Na[Na{N(SiMe(3))(2)AlMe(3)}(2)] are described. The structure is compo sed of an infinite array of bis(amido)sodate [Na{N(SiMe(3))(2)AlMe(3)} (2)](-) anions and Na+ cations, the latter being ''solvated'' by Na+-- -H3C- interactions alone.