NEW WATER-SOLUBLE RUTHENIUM(II) AND OSMIUM(II) HYDROXO CARBONYL-COMPLEXES

Authors
CARIATI E LUCENTI E PIZZOTTI M ROBERTO D UGO R
Citation
E. Cariati et al., NEW WATER-SOLUBLE RUTHENIUM(II) AND OSMIUM(II) HYDROXO CARBONYL-COMPLEXES, Organometallics, 15(20), 1996, pp. 4122-4124
Citations number
52
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
20
Year of publication
1996
Pages
4122 - 4124
Database
ISI
SICI code
0276-7333(1996)15:20<4122:NWRAOH>2.0.ZU;2-T
Abstract
A high-yield procedure is described for the preparation, from [M(CO)(3 )Cl-2](2) (M = Ru, Os) and aqueous NaOH, of the new water-soluble and air-stable species [Ru(CO)(2)Cl(OH)](n), [Ru(CO)(2)(OH)(2)](n), [Os(CO )(3)Cl(OH)](2), and [Os(CO)(3)(OH)(2)](x) (x = 2 or n).