SYNTHESIS AND CHARACTERIZATION OF BORON-CONTAINING FERROCENYL LIGANDSFOR ASYMMETRIC CATALYSIS

Authors
KIMMICH BFM LANDIS CR POWELL DR
Citation
Bfm. Kimmich et al., SYNTHESIS AND CHARACTERIZATION OF BORON-CONTAINING FERROCENYL LIGANDSFOR ASYMMETRIC CATALYSIS, Organometallics, 15(20), 1996, pp. 4141-4146
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
20
Year of publication
1996
Pages
4141 - 4146
Database
ISI
SICI code
0276-7333(1996)15:20<4141:SACOBF>2.0.ZU;2-3
Abstract
Novel boronato-functionalized ferrocenylphosphine ligands 3a-c have be en synthesized from o)-2-[1((1-hydroxy-2-phenyl)amino)ethyl]-ferrocene (2). These ligands form stable ligand-metal adducts with Rh(I) comple xes that are catalytically active in hydrogenation and hydroformylatio n reactions. The square-planar metal complex Pt(2)Me)I exhibits a stru cture that appears well-suited to support secondary interactions betwe en the Lewis acidic boron functionality and Lewis basic sites of funct ionalized, coordinated alkenes.