The measurement of temperature of heavy particles in a thermal plasma
is based on the comparison of experimental rotational spectrum obtaine
d by optical emission spectroscopy and synthetic spectra calculated fo
r different temperatures. The calculation principle of the synthetic s
pectra is detailed as well as the temperature accuracy obtained. This
method is used to measure the temperature of an Ar-CO2 mixture plasma
produced in a wall stabilized are with molecular spectra of C-2 (Swan
system) and CN (violet system).