SYNTHESIS AND IR-SPECTRAL CHARACTERIZATION OF MIXED-LIGAND SOLID-STATE COMPLEXES OF SOME LANTHANOIDES WITH MONO-(2-ETHYLHEXYL) PHOSPHORIC

Authors
ARNAUDOV M MILANOVA M TODOROVSKY D
Citation
M. Arnaudov et al., SYNTHESIS AND IR-SPECTRAL CHARACTERIZATION OF MIXED-LIGAND SOLID-STATE COMPLEXES OF SOME LANTHANOIDES WITH MONO-(2-ETHYLHEXYL) PHOSPHORIC, Spectroscopy letters, 29(7), 1996, pp. 1297-1305
Citations number
12
Categorie Soggetti
Spectroscopy
Journal title
Spectroscopy letters → ACNP
ISSN journal
00387010
Volume
29
Issue
7
Year of publication
1996
Pages
1297 - 1305
Database
ISI
SICI code
0038-7010(1996)29:7<1297:SAICOM>2.0.ZU;2-Z
Abstract
The synthesis of a new type of complexes of Y, Nd and Er with mono-(2- ethylhexyl) phosphoric acid is reported. The elemental composition, IR -spectral data and thermogravimetric analysis prove the presence of bo th mono- and bivalent ions of the acid as ligands as well as of NO3--i ons. The IR-spectrum is interpreted in comparison with those of other lanthanoid complexes of the same acid.