STEREOSELECTIVE SYNTHESIS OF PETROSTEROL AND A FORMAL SYNTHESIS OF ARAGUSTEROLS

Authors
HONDA T KATOH M YAMANE S
Citation
T. Honda et al., STEREOSELECTIVE SYNTHESIS OF PETROSTEROL AND A FORMAL SYNTHESIS OF ARAGUSTEROLS, Journal of the Chemical Society. Perkin transactions. I, (18), 1996, pp. 2291-2296
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
18
Year of publication
1996
Pages
2291 - 2296
Database
ISI
SICI code
0300-922X(1996):18<2291:SSOPAA>2.0.ZU;2-Q
Abstract
Stereoselective construction of a steroidal side chain containing a 26 -27 cyclopropane ring, compound 22, has been achieved by an intramolec ular cyclisation of the corresponding beta-methylsulfonyloxy cyanide 1 6, derived from a chiral cyclopentane derivative. Compound 22 has been further utilised in the synthesis of the naturally occurring steroid petrosterol 3.