SYNTHESIS OF (BA,K)(2)(PB,BI)O-4-DELTA

Authors
Citation
M. Licheron, SYNTHESIS OF (BA,K)(2)(PB,BI)O-4-DELTA, Materials science & engineering. B, Solid-state materials for advanced technology, 40(1), 1996, pp. 50-53
Citations number
13
Categorie Soggetti
Material Science","Physics, Condensed Matter
ISSN journal
09215107
Volume
40
Issue
1
Year of publication
1996
Pages
50 - 53
Database
ISI
SICI code
0921-5107(1996)40:1<50:SO(>2.0.ZU;2-F
Abstract
The synthesis of a new layered perovskite family is reported. The phas e (Ba1-xKx)(2)(Pb1-yBiy)O-4 is the n = 2 member of Ruddlesden-Popper s eries A(n+1)B(n)O(3n+1). The compounds have tetragonal symmetry and th eir space group is I4/mmm. Single phasic polycrystalline samples were obtained with K2NiF4-type structure for 0 less than or equal to x less than or equal to 0.2 and 0 less than or equal to y less than or equal to 0.3. The synthesis of these compounds was successful owing to a mo dified sol-gel method.