LIGAND COUPLING REACTIONS OF 2-PYRIDYL, 4-PYRIDYL AND 2-PYRIMIDYL SULFOXIDES WITH GRIGNARD-REAGENTS
Citation
S. Oae et al., LIGAND COUPLING REACTIONS OF 2-PYRIDYL, 4-PYRIDYL AND 2-PYRIMIDYL SULFOXIDES WITH GRIGNARD-REAGENTS, Phosphorus, sulfur and silicon and the related elements, 115, 1996, pp. 179-182
Categorie Soggetti
Chemistry Inorganic & Nuclear
SICI code
1042-6507(1996)115:<179:LCRO24>2.0.ZU;2-J
Abstract
The ligand coupling reaction was extended to 3- and 4-pyridyl sulfoxid
es as well as the 2-pyrimidyl moiety with Grignard reagents. It was fo
und that both 4-pyridyl and 2-pyrimidyl sulfoxides nicely underwent th
e ligand coupling reactions, but 3-pyridyl sulfoxide underwent ligand
exchange.