STATE-TO-STATE DIFFERENTIAL CROSS-SECTIONS FOR ROTATIONALLY INELASTIC-COLLISIONS OF NO((2)PI(1 2,)J=0.5) WITH AR AT KINETIC ENERGIES BETWEEN 117 CM(-1) AND 1694 CM(-1)/
Sd. Jons et al., STATE-TO-STATE DIFFERENTIAL CROSS-SECTIONS FOR ROTATIONALLY INELASTIC-COLLISIONS OF NO((2)PI(1 2,)J=0.5) WITH AR AT KINETIC ENERGIES BETWEEN 117 CM(-1) AND 1694 CM(-1)/, The Journal of chemical physics, 105(13), 1996, pp. 5397-5407
State-to-state differential cross sections have been measured for scat
tering of NO((2) Pi(1/2)j=0.5), Ar at kinetic energies of 117, 149, 44
2, and 1694 cm(-1). The differential cross sections at each collision
energy are presented as a function of final state (Omega',j') at const
ant center-of-mass scattering angle. Center-of-mass angular distributi
ons are also given for final rotational states ((2) Pi(1/2), j' = 1.5,
2.5, 8.5, 12.5, and 14.5) at a kinetic energy of 442 cm(-1), and for
J' = 18.5 at a kinetic energy of 1694 cm(-1). Rotational rainbow struc
ture is seen in both types of data. The results are generally in good
agreement with quantum scattering calculations carried out by Alexande
r [J. Chem. Phys. 99, 7725 (1993)] using newly calculated ab initio po
tential energy surfaces, and thus may serve as a new benchmark for the
microscopic dynamics of molecular energy transfer in open-shell molec
ules. (C) 1996 American Institute of Physics.