Mesoscopic superconducting loops exhibit a well-known h/2e periodic mo
dulation of the transition temperature T-c with the enclosed magnetic
flux Phi, which is due to the fluxoid quantization. We have found subs
tructures of this modulation in the magnetoresistance R(Phi) and the p
hase boundaries T-c(Phi) of microladders containing several square loo
ps of 1.4 mu m size. The substructures are due to transitions between
superconducting states differing in the order parameter profile and th
e flow pattern of the supercurrents. The experimental data are in exce
llent agreement with the theoretical phase boundaries obtained within
the de Gennes-Alexander approach for superconducting micronetworks.