Lj. Cabri et al., MINERALOGY AND DISTRIBUTION OF PLATINUM-GROUP MINERAL (PGM) PLACER DEPOSITS OF THE WORLD, Exploration and mining geology, 5(2), 1996, pp. 73-167
Citations number
226
Categorie Soggetti
Geology,"Geosciences, Interdisciplinary","Mining & Mineral Processing
Mineralogical studies of platinum-group minerals (PGM) made during the
period 1970-1995 are compiled in this paper for PGM obtained from pla
tinum- and gold-bearing placer deposits of fifteen countries. A total
of 3399 quantitative electron microprobe analyses of 37 different PGM
are presented, together with analytical data plotted on compositional
diagrams. The data reflect the dominance of Pt-Fe alloys (1723 analyse
s) and Os-Ir-Ru-Pt alloys (976 analyses) in the placers. The platinum-
group element (PGE) alloys, as well as some other PGM, generally occur
as grains less than one millimetre in size. The Pt-Fe alloys, contain
ing some Cu and Ni, are characterized by a wide range of Pt:(Fe, Cu, N
i) ratios and, where sufficient data are available, often show a bimod
al population at about 16-17 and 25 at.% (Fe, Cu, Ni). Iridium, osmium
, and rhodium occur in trace quantities in over 96% of the analyzed gr
ains, and all three elements were never found to be in concentrations
below their detection levels simultaneously. The large data base for t
he hexagonal alloys shows a well-developed trend parallelling the misc
ibility gap in the Os-Ir-Ru ternary system. New analyses have narrowed
further the width of this miscibility gap, which we postulate to be d
ue to the formation of some alloys at higher temperatures. Important f
eatures of the PGM alloys studied include the presence of inclusions o
f other PGM (as well as some undefined PGM), PGE-bearing minerals, spi
nels, silicates, and more rarely sulfides such as chalcopyrite, bornit
e, and pentlandite, as well as their crystallographic orientation and
textures. Alteration and replacement features (when present) are minor
, not pervasive, and usually restricted to a limited number of PGM. Th
e sum of the features obtained by detailed mineralogical characterizat
ion of the placer PGM is consistent with a high temperature intrusive
origin. Evidence of minor secondary alteration that is sometimes found
(e.g., irarsite, tulameenite) is probably associated with later proce
sses such as serpentinization. The presence of PGE-oxides and hydroxid
es (?), all of which are still incompletely characterized, is ascribed
to surficial weathering processes. In many cases the placer PGM can b
e traced to the source intrusive rocks (e.g., zoned ultramafic complex
, ophiolite). However, correlation with source rocks is sometimes not
possible due to deep weathering, lack of detailed geological maps, or
inacessible field areas. Copyright (C) 1996 Canadian Institute of Mini
ng, Metallurgy and Petroleum.