SYNTHESIS AND MID-IR ABSORPTION CROSS-SECTIONS OF BRNO2

Authors
FRENZEL A SCHEER V BEHNKE W ZETZSCH C
Citation
A. Frenzel et al., SYNTHESIS AND MID-IR ABSORPTION CROSS-SECTIONS OF BRNO2, Journal of physical chemistry, 100(41), 1996, pp. 16447-16450
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
41
Year of publication
1996
Pages
16447 - 16450
Database
ISI
SICI code
0022-3654(1996)100:41<16447:SAMACO>2.0.ZU;2-A
Abstract
A method for the synthesis of gaseous BrNO2 at concentrations of the o rder of 10(-9) mol/cm(3) at atmospheric pressure is described, based o n the heterogeneous reaction of ClNO2 with aqueous bromide solutions. We measured the gas-phase infrared absorption cross sections in the ra nge 700-1800 cm(-1). The matrix isolation spectrum was recorded for id entification by comparison with literature data.