FLOW BIREFRINGENCE AND CONFORMATION OF PO LY(DIPHENYLENE SULFONE TEREPHTHALAMIDE)

Authors
SHTENNIKOVA IN FILIPPOVA TV VOLOKHINA AV LAVRENKO PN
Citation
In. Shtennikova et al., FLOW BIREFRINGENCE AND CONFORMATION OF PO LY(DIPHENYLENE SULFONE TEREPHTHALAMIDE), Vysokomolekularnye soedinenia. Seria A, 38(8), 1996, pp. 1320-1327
Citations number
12
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
38
Issue
8
Year of publication
1996
Pages
1320 - 1327
Database
ISI
SICI code
0507-5475(1996)38:8<1320:FBACOP>2.0.ZU;2-7
Abstract
Optical and hydrodynamic properties of poly(diphenylene sulfone tereph thalamide) in sulfuric acid were studied using flow birefringence and viscometry. Optical anisotropies of the molecular segment and monomer unit and equilibrium rigidity of the entire macromolecule were evaluat ed from the experimental plot of the optical shear coefficient versus molecular mass. The macromolecules of the studied heterocyclic polyami de were found to possess the conformation of a kinetically rigid coil.