The association of polyblock copolymer, poly(siloxane-co-carbonate-co-
urethane), in benzene (selective solvent for siloxane component) was s
tudied by light scattering, viscometry, and sedimentation methods. Ano
malous micellization was observed in a solution in the concentration r
ange of 0.02-1.4 g/dl: as the concentration increases, the associates
pass through the region of metastable microphase separation and then f
orm polymolecular micelles.