SYNTHESIS OF ORGANOCYCLOCARBOSILOXANE POL YMERS BY HYDROSILYLATION WITH VARIOUS PLATINUM COMPLEXES

Authors
ASTAPOVA TV MAKAROVA NN
Citation
Tv. Astapova et Nn. Makarova, SYNTHESIS OF ORGANOCYCLOCARBOSILOXANE POL YMERS BY HYDROSILYLATION WITH VARIOUS PLATINUM COMPLEXES, Vysokomolekularnye soedinenia. Seria A, 38(8), 1996, pp. 1442-1444
Citations number
7
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
38
Issue
8
Year of publication
1996
Pages
1442 - 1444
Database
ISI
SICI code
0507-5475(1996)38:8<1442:SOOPYB>2.0.ZU;2-#
Abstract
The effect of different forms of Pt complex catalysts on the structure of cyclolinear carbosiloxane polymers in polyaddition reactions was s tudied by gel permeation chromatography and Si-29 NMR spectroscopy. Us ing poly(hexaethylcyclotetrasiloxane-2,6-ethylene) as an example, it w as shown that the use of the catalyst in colloidal form decreases the polydispersity of the polymer, in contrast to the unreduced complex ca talysts.