Evidence for electron capture of Te-123 from the K shell has been obta
ined in an experiment performed underground with an array of four 340
g TeO2 thermal detectors. This is the first real proof of the decay of
this isotope. In our thermal approach, unlike in previous experiments
, the TeO2 bolometer acts at the same time as source and detector of t
he Te-123 decay and its resolution allows to discriminate between the
lines produced by background x ray excitation and electron capture. In
addition anticoincidence with the nearby detectors reduces the signal
of x rays produced by excitation of Tellurium. The partial width for
K electron capture of Te-123 is the smallest one ever measured for a s
ingle beta process and lower by six orders of magnitude with respect t
o the previously reported one for this decay. An analysis based on the
expected fraction of electron captures accompanied by internal bremss
trahlung allows to set a stringent limit, independent on the decay cha
nnel, for the lifetime of Te-123.