SYNTHESIS AND DYNAMIC BEHAVIOR OF NEW METALLO-BASED STERICALLY OVERCROWDED ALKENES

Authors
SMID WI SCHOEVAARS AM KRUIZINGA W VELDMAN N SMEETS WJJ SPEK AL FERINGA BL
Citation
Wi. Smid et al., SYNTHESIS AND DYNAMIC BEHAVIOR OF NEW METALLO-BASED STERICALLY OVERCROWDED ALKENES, Chemical communications, (19), 1996, pp. 2265-2266
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
19
Year of publication
1996
Pages
2265 - 2266
Database
ISI
SICI code
1359-7345(1996):19<2265:SADBON>2.0.ZU;2-2
Abstract
The synthesis and crystal and molecular structures of novel metallo-ba sed sterically overcrowded alkenes are reported and dynamic H-1 NMR st udies reveals that the isomerization barriers are dramatically increas ed on metal coordination.