The electrical properties of the P-b center have been measured using t
he conductance technique over the temperature range 130-290 K. A high
concentration of P-b centers was created by vacuum annealing of 28-nm-
thick thermal oxides on (111) silicon surfaces. Fitting the conductanc
e data allowed the contribution of the (0/-) P-b level to be separated
from the U-shaped background states. The (0/-) peak in the density of
states was found to be asymmetrical with a broad shoulder on the cond
uction band side. The P-b levels were found to show a capture cross se
ction which fell toward the band edges and which could be fitted by as
suming an activated cross section with an activation energy which incr
eased toward the band edges. By contrast, the background states showed
a cross section which was temperature and band bending independent.