The effect of porosity on tile complex dielectric permittivity of micr
owave sintered zinc oxide at room temperature and 2.45 GHz is reported
. The predictions of conventional Maxwell-Garnet theory and the effect
ive medium approximation art in poor agreement with the experimental r
esults, Various methods are employed to investigate the system in an e
ffort to come up with new mixing laws, including combinations of these
two analytic theories and finite difference electromagnetic simulatio
ns of representative microstructures. A model that assumes the existen
ce of dielectrically inactive, fractal-geometry boundaries between cer
amic grains provides an excellent description of the results with no f
ree parameters. It gives physical insight into the experimentally obse
rved mixing law. (C) 1996 American Institute of Physics.