TECHNOLOGICAL PARAMETERS IN THE SYNTHESIS OF 1,1,1-TRICHLOROETHANE FROM VINYLIDENE-CHLORIDE

Authors
MILCHERT E GOC W STEFANSKA J PAZDZIOCH W
Citation
E. Milchert et al., TECHNOLOGICAL PARAMETERS IN THE SYNTHESIS OF 1,1,1-TRICHLOROETHANE FROM VINYLIDENE-CHLORIDE, Industrial & engineering chemistry research, 35(10), 1996, pp. 3290-3294
Citations number
10
Categorie Soggetti
Engineering, Chemical
Journal title
Industrial & engineering chemistry research → ACNP
ISSN journal
08885885
Volume
35
Issue
10
Year of publication
1996
Pages
3290 - 3294
Database
ISI
SICI code
0888-5885(1996)35:10<3290:TPITSO>2.0.ZU;2-J
Abstract
The optimum parameters in the synthesis of 1,1,1-trichloroethane durin g the reaction between vinylidene chloride and hydrogen chloride are a s follows: temperature, 22 degrees C; catalyst (FeCl3) concentration, 0.3% by weight;, equimolar ratio of raw materials; VDC flow rate, 0.22 -0.23 cm(3) cm(-3) h(-1). Changing these parameters does not result in considerable change in the product yield.