S. Bandyopadhyay et al., TRANSIENT-BEHAVIOR OF A COCONUT SHELL PYROLYZER - A MATHEMATICAL-ANALYSIS, Industrial & engineering chemistry research, 35(10), 1996, pp. 3347-3355
A mathematical model based on the mechanistic approach to the reaction
kinetics of pyrolysis reactions and the realistic analysis of the int
eraction between simultaneous heat and mass transfer along with the ch
emical reaction has been developed for the design of smoothly running
pyrolyzers. The model of a fixed-bed pyrolysis reactor has been propos
ed on the basis of the dimensionless parameters with respect to time a
nd radial position. The variation of physical parameters like bed void
age, heat capacity, diffusivity, density, thermal conductivity, etc.,
on temperature and conversion has been taken into account. A deactivat
ion model has also been incorporated to explain the behavior of pyroly
sis reactions at temperaures above 673 K. The simulated results of the
model have been explained by comparing them with the experimental res
ults.