PALLADIUM(II)-CATALYZED HYDROESTERIFICATION OF ENOL ESTERS - REMARKABLE ALPHA-SUBSTITUENT EFFECT UPON REGIOSELECTIVITY

Authors
KUDO K OIDA Y MORI S KOMATSU K SUGITA N
Citation
K. Kudo et al., PALLADIUM(II)-CATALYZED HYDROESTERIFICATION OF ENOL ESTERS - REMARKABLE ALPHA-SUBSTITUENT EFFECT UPON REGIOSELECTIVITY, Reaction kinetics and catalysis letters, 59(1), 1996, pp. 29-33
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
59
Issue
1
Year of publication
1996
Pages
29 - 33
Database
ISI
SICI code
0133-1736(1996)59:1<29:PHOEE->2.0.ZU;2-I
Abstract
Pd(II)-catalyzed hydroesterification of various enol esters smoothly p roceeded upon the combined use of pressurized carbon monoxide and meth anol to give the alpha- or beta-acetoxy esters with the regioselectivi ty highly depending on the size of the alpha-substituent.