KINETICS AND CATALYSIS BY NAY ENTRAPPED PT CARBONYL CLUSTERS IN THE CO+NO REACTION

Authors
LI GJ ICHIKAWA M GUO XX
Citation
Gj. Li et al., KINETICS AND CATALYSIS BY NAY ENTRAPPED PT CARBONYL CLUSTERS IN THE CO+NO REACTION, Reaction kinetics and catalysis letters, 59(1), 1996, pp. 75-86
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
59
Issue
1
Year of publication
1996
Pages
75 - 86
Database
ISI
SICI code
0133-1736(1996)59:1<75:KACBNE>2.0.ZU;2-0
Abstract
[Pt(CO)(24)](2-)/NaY and [Pt-9(CO)(18)](2-)/NaY exhibited much higher activities in the CO+NO reaction at 473 K compared with Pt/Al2O3. Kine tic study and in-situ FT-IR results suggest that NO adsorption is the rate-limiting step in the CO+NO reaction on intrazeolite Pt carbonyl c lusters.