SYNTHESIS, STRUCTURE, AND CHARACTERIZATION OF THE HYDROGEN-SUBSTITUTED IMIDO COMPLEX TICL(NH)(OPPH(3))(2)

Authors
MCKARNS PJ YAP GPA RHEINGOLD AL WINTER CH
Citation
Pj. Mckarns et al., SYNTHESIS, STRUCTURE, AND CHARACTERIZATION OF THE HYDROGEN-SUBSTITUTED IMIDO COMPLEX TICL(NH)(OPPH(3))(2), Inorganic chemistry, 35(21), 1996, pp. 5968
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
21
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:21<5968:SSACOT>2.0.ZU;2-2
Abstract
The first hydrogen-substituted imido complex of the group 4 metals has been synthesized. Its crystal structure shows the titanium atom in sq uare pyramidal geometry with a very short titanium-nitrogen bond lengt h. This complex represents a structural model for species that have be en frequently proposed as intermediates in chemical vapor deposition p rocesses.