REACTION OF NS+ WITH N-3(-)

Authors
KLAPOTKE TM SCHULZ A
Citation
Tm. Klapotke et A. Schulz, REACTION OF NS+ WITH N-3(-), Polyhedron, 15(24), 1996, pp. 4387-4390
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
24
Year of publication
1996
Pages
4387 - 4390
Database
ISI
SICI code
0277-5387(1996)15:24<4387:RONWN>2.0.ZU;2-9
Abstract
Thionitrosyl hexafluoroarsenate, [NS][AsF6], reacted with caesium azid e, [Cs][N-3], to form S2N2 which polymerized to give (SN)(x). The stru ctures of the following likely intermediate species were calculated at correlated MP2/6-31G(d,p) level of theory (relative energies in kcal mol(-1)) : thionitrosyl azide, N-3-N=S (37.8), thiazyl azide, N-3-S=N (39.2) and cyclic N4S (0.0). Copyright (C) 1996 Elsevier Science Ltd