THE FIRST TETRANUCLEAR VANADIUM(V) PEROXO COMPLEX - PREPARATION, VIBRATIONAL-SPECTRA AND X-RAY CRYSTAL-STRUCTURE OF K-7[V4O4(O-2)(8)(PO4)]CENTER-DOT-9H(2)O

Authors
SCHWENDT P ORAVCOVA A TYRSELOVA J PAVELCIK F MAREK J
Citation
P. Schwendt et al., THE FIRST TETRANUCLEAR VANADIUM(V) PEROXO COMPLEX - PREPARATION, VIBRATIONAL-SPECTRA AND X-RAY CRYSTAL-STRUCTURE OF K-7[V4O4(O-2)(8)(PO4)]CENTER-DOT-9H(2)O, Polyhedron, 15(24), 1996, pp. 4507-4511
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
24
Year of publication
1996
Pages
4507 - 4511
Database
ISI
SICI code
0277-5387(1996)15:24<4507:TFTVPC>2.0.ZU;2-T
Abstract
The vanadium(V) peroxo phosphato complex K-7[V4O4(O-2)(8)(PO4)]. 9H(2) O has been obtained from the KVO3-KH2PO4-KOH-H2O2-H2O-C2H5OH system. T he X-ray structural analysis revealed a tetranuclear anionic structure in which two dinuclear [V2O2(O-2)(2)(mu-eta(1):eta(2)-O-2)(2)] units are connected by the mu(4)-PO4 group. Copyright (C) 1996 Elsevier Scie nce Ltd