We propose a model-independent method to extract a linear combination
of the s-wave pi-pi scattering lengths by measuring the gamma gamma de
cay branching ratio for a tagged sample of pi(+)pi(-) atoms (pionium).
In the first experimental search for an appropriate tagging reaction,
we observed sigma(tot)=76+/-21+/-11 pb for free pion pair production
in pd-->He-3 pi(+)pi(-) 1.0 MeV above threshold. This result suggests
a pionium production cross section less than or similar to 1 pb.