Space- and time-resolved spectroscopy is used to measure properties of
several-keV Li atoms in a 20 TW ion diode. These measurements but in
the diode anode-cathode gap are used in a charge-exchange model for th
e Li atom production in order to obtain the Li+ beam angular divergenc
e within 50 mu m of the LiF-coated anode surface. This ion divergence
near the surface is surprisingly large, and accounts for about half th
e typical 25 mrad final accelerated-beam divergence. The measurements
provide constraints for models attempting to explain highly diverging
ion emission from thin alkali-halide films in similar to 10 MV/cm appl
ied fields.