DYNAMIC PROPERTIES OF SEMIDILUTE SOLUTIONS AT THE THETA-POINT

Citation
M. Adam et al., DYNAMIC PROPERTIES OF SEMIDILUTE SOLUTIONS AT THE THETA-POINT, Physical review letters, 77(17), 1996, pp. 3673-3676
Citations number
21
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
77
Issue
17
Year of publication
1996
Pages
3673 - 3676
Database
ISI
SICI code
0031-9007(1996)77:17<3673:DPOSSA>2.0.ZU;2-W
Abstract
Here we report results obtained by neutron spin echo on semidilute the ta solutions of polystyrene in deuterated cyclohexane. It is shown tha t the pertinent length for the diffusion coefficient is not the correl ation length xi(theta) of concentration fluctuations but rather the di stance between binary contacts. At length scales smaller than this dis tance, the dynamics is linked to the local viscosity, which is found t o be surprisingly concentration and temperature dependent.