T. Takamiya et al., INFLUENCE OF HEAT-TREATMENT BEFORE SECONDARY RECRYSTALLIZATION ON MAGNETIC-PROPERTIES OF 3-PERCENT SI GRAIN-ORIENTED STEEL CONTAINING SB, Journal of magnetism and magnetic materials, 160, 1996, pp. 131-132
The secondary recrystallization of 3% Si grain-oriented steel containi
ng Sb has been investigated. The mechanism of the improvement of the m
agnetic properties under the conditions of Sb addition and a constant
temperature treatment during secondary recrystallization has been clar
ified by three experiments. It has been found that (1) Sb segregation
in grain boundaries during decarburization annealing retards decarburi
zation and grain growth, so that the {110} intensity increases acid th
e grain size decreases with increasing Sb; (2) the constant temperatur
e treatment for final annealing enhances the Sb segregation in grain b
oundaries, and therefore maintains the {110} intensity in the specimen
with the addition of Sb; and (3) the addition of Sb increases the inh
ibiting force. These three effects enable secondary recrystallization
such that many (110)[001] nuclei grow rapidly, surrounded by small pri
mary grains, leading to high B-s values.