ON THE INTERMEDIATES OF THE ACETIC-ACID REACTIONS ON OXIDES - AN IR STUDY

Authors
PEI ZF PONEC V
Citation
Zf. Pei et V. Ponec, ON THE INTERMEDIATES OF THE ACETIC-ACID REACTIONS ON OXIDES - AN IR STUDY, Applied surface science, 103(2), 1996, pp. 171-182
Citations number
40
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical","Materials Science, Coatings & Films
Journal title
Applied surface science → ACNP
ISSN journal
01694332
Volume
103
Issue
2
Year of publication
1996
Pages
171 - 182
Database
ISI
SICI code
0169-4332(1996)103:2<171:OTIOTA>2.0.ZU;2-G
Abstract
Adsorption of acetic acids has been studied by FT-IR on a series of ad sorbents, known as good catalysts for the selective hydrogenation of c arboxylic acids to corresponding aldehydes: SnO2, TiO2, Pt/SnO2, Pt/Ti O2. Very similar adsorbed species are observed by FT-IR with all menti oned catalysts. The catalysts differ mainly by their behaviour upon in creasing temperature program. The strongly bound unidentate or the bid entate, bound to the oxide, are the possible intermediates of the cata lytic reaction to acetaldehyde.