The structural properties of GaAs grown at low temperatures by molecul
ar beam epitaxy (LTMBE GaAs) were studied. The excess arsenic atoms in
LTMBE GaAs exist in the form of arsenic interstitial couples (i,e, tw
o ns atoms share the one host site), and cause an increase in the latt
ice parameter of LTMBE GaAs. Annealing at above 300 degrees C, the ars
enic interstitial couples decomposed, and As precipitates formed, resu
lting in a decrease in the lattice parameter.