(ISOCYANIDE)GOLD(I) THIOSALICYLATES - SUPRAMOLECULAR ASSEMBLY BASED ON BOTH AURIOPHILIC AND HYDROGEN-BONDING

Authors
SCHNEIDER W BAUER A SCHMIDBAUR H
Citation
W. Schneider et al., (ISOCYANIDE)GOLD(I) THIOSALICYLATES - SUPRAMOLECULAR ASSEMBLY BASED ON BOTH AURIOPHILIC AND HYDROGEN-BONDING, Organometallics, 15(26), 1996, pp. 5445-5446
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
26
Year of publication
1996
Pages
5445 - 5446
Database
ISI
SICI code
0276-7333(1996)15:26<5445:(T-SAB>2.0.ZU;2-Z
Abstract
Reaction of(RNC)AuCl[R=tert-butyl (1a), mesityl (1b)] with sodium thio salicylate in the two-phase system water/dichloromethane gives high yi elds of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffr action studies. The supramolecular structure of both compounds is gove rned by Au-Au interactions [2a, Au-Au 3.157(2) Angstrom; 2b, Au-Au 3.3 186(5) Angstrom] and hydrogen bonding through the carboxylic acid grou ps.