BINDING OF A MESO-OCTAETHYL TRIS(PYRROLE)-MONO(PYRIDINE) LIGAND TO TITANIUM(III) AND TITANIUM(IV) - A MONOMERIC TITANIUM(IV) OXO BIS(PYRIDINE)-BIS(PYRROLE) COMPLEX DERIVED FROM THE C-O BOND-CLEAVAGE OF CARBON-MONOXIDE

Authors
CRESCENZI R SOLARI E FLORIANI C CHIESIVILLA A RIZZOLI C
Citation
R. Crescenzi et al., BINDING OF A MESO-OCTAETHYL TRIS(PYRROLE)-MONO(PYRIDINE) LIGAND TO TITANIUM(III) AND TITANIUM(IV) - A MONOMERIC TITANIUM(IV) OXO BIS(PYRIDINE)-BIS(PYRROLE) COMPLEX DERIVED FROM THE C-O BOND-CLEAVAGE OF CARBON-MONOXIDE, Organometallics, 15(26), 1996, pp. 5456-5458
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
26
Year of publication
1996
Pages
5456 - 5458
Database
ISI
SICI code
0276-7333(1996)15:26<5456:BOAMTL>2.0.ZU;2-T
Abstract
The reaction. of a Ti-Me species with carbon monoxide occurred with th e complete cleavage of the C-O bond and formation of the Ti=O unit, wh ile the [Me-C] fragment homologated a pyrrole to a 4-methylpyridine ri ng within the meso-octaethyl tris(pyrrole)mono(pyridine) macrocycle.