P-ANISALDYHYDE AS A LIGAND IN MOLYBDENUM AND TUNGSTEN COMPLEXES - SIGMA OR PI

Authors
SCHUSTER DM WHITE PS TEMPLETON JL
Citation
Dm. Schuster et al., P-ANISALDYHYDE AS A LIGAND IN MOLYBDENUM AND TUNGSTEN COMPLEXES - SIGMA OR PI, Organometallics, 15(26), 1996, pp. 5467-5469
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
26
Year of publication
1996
Pages
5467 - 5469
Database
ISI
SICI code
0276-7333(1996)15:26<5467:PAALIM>2.0.ZU;2-R
Abstract
The different binding modes of p-anisaldehyde to the [TpMo(CO)(MeC=CMe )](+) and [TpW(CO)(MeC=CMe)](+) fragments in solution have been assess ed by IR and H-1 and C-13 NMR spectra. X-ray analyses substantiate tha t p-anisaldehyde is a-bound in, the molybdenum complex 1 and pi-bound in the tungsten complex 2.