THE FIRST ISOLATION AND STRUCTURAL CHARACTERIZATION OF A LANTHANOID -IMINE AZAMETALLACYCLOPROPANE COMPLEX, [YB(ETA(2)-PH(2)CNPH)(HMPA)(3)]

Authors
MAKIOKA Y TANIGUCHI Y FUJIWARA Y TAKAKI K HOU ZM WAKATSUKI Y
Citation
Y. Makioka et al., THE FIRST ISOLATION AND STRUCTURAL CHARACTERIZATION OF A LANTHANOID -IMINE AZAMETALLACYCLOPROPANE COMPLEX, [YB(ETA(2)-PH(2)CNPH)(HMPA)(3)], Organometallics, 15(26), 1996, pp. 5476-5478
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
26
Year of publication
1996
Pages
5476 - 5478
Database
ISI
SICI code
0276-7333(1996)15:26<5476:TFIASC>2.0.ZU;2-E
Abstract
A dianionic lanthanoid(II)-imine azametallacyclopropane complex, [Yb(e ta(2)-Ph(2)CNPh)(hmpa)(3)] (hmpa=hexamethylphosphoramide), has been di rectly synthesized by the reaction of ytterbium metal with N-(diphenyl methylidene)aniline in THF/HMPA and structurally characterized by X-ra y analysis.