[SI(HNCH2CH2)(2)(NCH2CH2)N](2) - A NOVEL PRODUCT OF HYDROGEN ELIMINATION FROM HSI(HNCH2CH2)(3)N

Authors
WAN YJ VERKADE JG
Citation
Yj. Wan et Jg. Verkade, [SI(HNCH2CH2)(2)(NCH2CH2)N](2) - A NOVEL PRODUCT OF HYDROGEN ELIMINATION FROM HSI(HNCH2CH2)(3)N, Organometallics, 15(26), 1996, pp. 5769-5771
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
26
Year of publication
1996
Pages
5769 - 5771
Database
ISI
SICI code
0276-7333(1996)15:26<5769:[-ANPO>2.0.ZU;2-O
Abstract
Rather than oligomers, the title dimer is formed in high yield by dehy drogenation of HSi(HNCH2CH2)(3)N under a variety of conditions ranging from 77% by pyrolysis at 200 degrees C to 95% by dimerization in liqu id ammonia in the presence of a catalytic amount of NaNH2. The structu re of the dimer was confirmed by X-ray crystallographic studies.