SPECIFICATION OF CHIRALITY FOR LINKS AND KNOTS

Citation
Cz. Liang et al., SPECIFICATION OF CHIRALITY FOR LINKS AND KNOTS, Journal of mathematical chemistry, 19(3-4), 1996, pp. 241-263
Citations number
25
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
19
Issue
3-4
Year of publication
1996
Pages
241 - 263
Database
ISI
SICI code
0259-9791(1996)19:3-4<241:SOCFLA>2.0.ZU;2-4
Abstract
A general scheme has been developed for the assignment of chirality de scriptors to chiral links and knots. For oriented links and knots, the new D/L scheme employs linking numbers, self-writhes, and writhe prof iles, in descending hierarchical order, with self-writhes and writhe p rofiles limited to alternating links and knots. A related scheme appli es to non-oriented links and knots. In a modification of a previous sc heme, the use of vertex-bicolored digraphs is introduced in order to c ompute writhe profiles of oriented links and knots. It is pointed out that even though the different geometric presentations of each individ ual chiral knot or link can be partitioned into homochirality classes, the links and knots that belong to a given configurational class, D o r L, are not homochirally similar.